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The functions of different components in acrylic ester adhesive

The formulation of acrylic ester adhesive from Table 1 to Table 4

Ingredient

Mass of each unit

Function

Methyl -a- cyanoacrylate

100

Methyl-a- cyanoacrylate

Polyalkylcyanoacrylate

3

Thickener to improve viscosity

Hydroquinone

1

Stabilizer to prolong the shelf life

邻苯二甲故二丁酯

3

Plasticizer to improve the brittleness of adhesive layer

Sulfur dioxide

0.1

Stabilizer to prolong the stability

KH-550

0.5

Coupling agent to improve bonding strength

 

 

 Table 2  The formulation of acrylic ester as primer

Components

Ingredient

Mass of each unit

Function

Primary agent

Hydroxyethyl methacrylate

63

Monomer to cure into solid structure

 

MMA
三缩四乙二醇二甲基丙烯酸酯热塑件聚氨酯
Hydroquinone

10 4 20 0.01

Monomer to improve curing speed.

Diester to improve curing speed and toughness

稳定剂Stabilizer,增加胶液的(原文不完整)

Primer

N-(2-Pyridyl)thiourea

5

accelerator promoter

 

methanol

50

solvent

 

乙肮

45

solvent

Adhesive and property

 Firstly, use the primer on the substrates. Then use the primary agent after solvent evaporation. The primary curing time and entire curing time are 1min and 24 hours respectively. And the peel strength is 5N/mm. The shear strength is 20MPa.

 

 Table 3The formulation of  acrylic ester as double primary agent

Components and properties

Ingredient

Mass of each unit

Function

 

methyl methacrylat

50~70

Monomer

 

methacrylic acid

5~20

Monomer to improve curing speed

 

Hydroquinone

0.01~0.1

Stabilizer

Composition A

Antioxidant agent

0.01~10

Antioxidant agent

 

ethylene glycol

0.5~5

Solvent and antifreeze

 

⑽Resin

15~20

粗料、 reinforcing agents

 

异丙苯过氧化氡

1~5

initiator

 

methyl methacrylat

50~70

笮体

 

methacrylic acid

5~20

苹体.捉商固化逨度

 

Hydroquinone

0.01~0.1

铨定剂

Composition B

丁晴椎胶

15~30

增曲剂

 

胺类促进剂

0.5^3

accelerator promoter

 

取代基硫脲

0.5~5

accelerator promoter

 

vanadium accelerator promoter

0.01~2

accelerator promoter

Proportion and property

Composition A and are based on 1:1.

The primary curing time is tested in 25℃.

Shear strength >25MPa

 

Table 4  The formulation of anaerobic adhesive

Components

Mass of each unit

Function 

三箱四乙二醉二甲基丙烯酸酯
EpoxyAcrylic diester
过氧化羟基二异丙苯
三乙胶
acrylic
Saccharin
气象白炭黑
phenylate

 

60 40 5
2
2
0.3
0.5
0.01

Monomer and disester
Modified resin oligome

initiator
accelerator promoter to improve curing speed.
Compounding agent to improve curing reaction

Accelerator promoter to improve curing speed.

Thixotropic agents to improve the  flowable.

Stabilizer to improve the storage stability.

Curing time and properties

 

M10 bolt. Curing time is about 10~20min.

Failure torque is 25~30N.m


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